The Reaction of 3-Cyano-2-methyl-1-phenylisothiourea with Isocyanate, Isothiocyanate and Carbodiimide.
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منابع مشابه
Methyl c-1-cyano-t-2-methylsulfonyl-3-phenylcyclopropanecarboxylate
The title compound, C(13)H(13)NO(4)S, is a racemic mixture of enanti-omers. Short intra-molecular contacts between sulfonyl O and ester carbonyl C atoms are observed [C⋯O = 2.881 (1), 2.882 (1) and 2.686 (1) Å], indicating the possibility of donor-acceptor inter-actions between these groups. The dihedral angle between the phenyl and cyclopropyl rings is 79.3 (1)°.
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The reaction between vinylene trithiocarbonate and chlorosulfonyl isocyanate proceeds by initial attack of thiocarbonyl on the isocyanate carbon.
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1996
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1996.845